Marvel's Ultimate Spider-Man : Season 4

Peter Parker finds himself in prime position – he’s a successful hero after fighting alongside The Avengers, a S.H.I.E.L.D. Academy leader and has a great relationship with his Aunt May. However, when Spidey discovers that his greatest enemies – Doctor Octopus, Hydra and the all-new Sinister 6 – have teamed up to destroy him and S.H.I.E.L.D., he creates a special new team of Spiders.